Walther Kossel
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Walther Ludwig Julius Kossel (4 January 1888 – 22 May 1956) was a
German German(s) may refer to: * Germany (of or related to) ** Germania (historical use) * Germans, citizens of Germany, people of German ancestry, or native speakers of the German language ** For citizens of Germany, see also German nationality law **Ge ...
physicist A physicist is a scientist who specializes in the field of physics, which encompasses the interactions of matter and energy at all length and time scales in the physical universe. Physicists generally are interested in the root or ultimate caus ...
known for his theory of the
chemical bond A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...
(
ionic bond Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities, and is the primary interaction occurring in ionic compounds. ...
/
octet rule The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The rule i ...
),
Sommerfeld–Kossel displacement law The Sommerfeld–Kossel displacement law states that the first spark (singly ionized) spectrum of an element is similar in all details to the arc (neutral) spectrum of the element preceding it in the periodic table. Likewise, the second (doubly ion ...
of atomic spectra, the Kossel-Stranski model for crystal growth, and the Kossel effect. Walther was the son of
Albrecht Kossel Ludwig Karl Martin Leonhard Albrecht Kossel (; 16 September 1853 – 5 July 1927) was a German biochemist and pioneer in the study of genetics. He was awarded the Nobel Prize for Physiology or Medicine in 1910 for his work in determining the che ...
who won the
Nobel Prize in Physiology or Medicine The Nobel Prize in Physiology or Medicine is awarded yearly by the Nobel Assembly at the Karolinska Institute for outstanding discoveries in physiology or medicine. The Nobel Prize is not a single prize, but five separate prizes that, accord ...
in 1910.


Career

Kossel was born in
Berlin Berlin ( , ) is the capital and largest city of Germany by both area and population. Its 3.7 million inhabitants make it the European Union's most populous city, according to population within city limits. One of Germany's sixteen constitue ...
, and began studies at the
University of Heidelberg } Heidelberg University, officially the Ruprecht Karl University of Heidelberg, (german: Ruprecht-Karls-Universität Heidelberg; la, Universitas Ruperto Carola Heidelbergensis) is a public research university in Heidelberg, Baden-Württemberg, ...
in 1906, but was at the
University of Berlin Humboldt-Universität zu Berlin (german: Humboldt-Universität zu Berlin, abbreviated HU Berlin) is a German public research university in the central borough of Mitte in Berlin. It was established by Frederick William III on the initiative o ...
during 1907 and 1908. In 1910, he became assistant to
Philipp Lenard Philipp Eduard Anton von Lenard (; hu, Lénárd Fülöp Eduárd Antal; 7 June 1862 – 20 May 1947) was a Hungarian-born German physicist and the winner of the Nobel Prize for Physics in 1905 for his work on cathode rays and the discovery of m ...
, who was also his thesis advisor. Kossel was awarded his Ph.D. in 1910, and he stayed on as assistant to Leonard until 1913. In 1913, the year in which
Niels Bohr Niels Henrik David Bohr (; 7 October 1885 – 18 November 1962) was a Danish physicist who made foundational contributions to understanding atomic structure and quantum theory, for which he received the Nobel Prize in Physics in 1922. B ...
introduced the
Bohr model In atomic physics, the Bohr model or Rutherford–Bohr model, presented by Niels Bohr and Ernest Rutherford in 1913, is a system consisting of a small, dense nucleus surrounded by orbiting electrons—similar to the structure of the Solar Syste ...
of the atom, Kossel went to the
University of Munich The Ludwig Maximilian University of Munich (simply University of Munich or LMU; german: Ludwig-Maximilians-Universität München) is a public research university in Munich, Germany. It is Germany's List of universities in Germany, sixth-oldest u ...
as assistant to
Arnold Sommerfeld Arnold Johannes Wilhelm Sommerfeld, (; 5 December 1868 – 26 April 1951) was a German theoretical physicist who pioneered developments in atomic and quantum physics, and also educated and mentored many students for the new era of theoretica ...
, under whom he did his
Habilitation Habilitation is the highest university degree, or the procedure by which it is achieved, in many European countries. The candidate fulfills a university's set criteria of excellence in research, teaching and further education, usually including a ...
. Under Sommerfeld, Munich was a theoretical center for the developing
atomic theory Atomic theory is the scientific theory that matter is composed of particles called atoms. Atomic theory traces its origins to an ancient philosophical tradition known as atomism. According to this idea, if one were to take a lump of matter a ...
, especially from the interpretation of
atomic spectra Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wa ...
. Kossel worked with Bohr and Sommerfeld on the Bohr-Sommerfeld model of the atom. In 1916, Kossel put forth his theory of the ionic chemical bond (
octet rule The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The rule i ...
), also independently advanced in the same year by Gilbert N. Lewis. In papers published in 1914, 1916, and 1920, Kossel was the first to explain the theory of absorption limits in
x-ray spectra X-ray spectroscopy is a general term for several spectroscopic techniques for characterization of materials by using x-ray radiation. Characteristic X-ray spectroscopy When an electron from the inner shell of an atom is excited by the energy o ...
. The edge appears at a critical frequency where absorption of the radiation largely begins with the resultant ejection of
photoelectrons The photoelectric effect is the emission of electrons when electromagnetic radiation, such as light, hits a material. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, and solid st ...
. In 1919, Kossel and Sommerfeld explained the similarity of the
atomic spectra Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter wa ...
of neutral atoms, of
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
Z, and singly ionized atoms, of atomic number Z + 1, which became known as the
Sommerfeld–Kossel displacement law The Sommerfeld–Kossel displacement law states that the first spark (singly ionized) spectrum of an element is similar in all details to the arc (neutral) spectrum of the element preceding it in the periodic table. Likewise, the second (doubly ion ...
. In 1920, Kossel explained another phenomenon of x-ray spectra. Under high resolution spectroscopy, the absorption edge has structure. He attributed this to absorption of radiation by electrons which are not ejected from matter as photoelectrons, but are “kicked up” to higher, unoccupied, bound electron energy levels. In early years, this was known as “ Kossel structure.” In 1921, Kossel took an appointment as ordinarius professor of theoretical physics at the
University of Kiel Kiel University, officially the Christian-Albrecht University of Kiel, (german: Christian-Albrechts-Universität zu Kiel, abbreviated CAU, known informally as Christiana Albertina) is a university in the city of Kiel, Germany. It was founded in ...
.American Philosophical Society Author Catalog: Kossel
/ref> In 1928, he put forth his kinetic theory of crystal growth, which became known as the Kossel-Stranski model
Iwan N. Stranski Ivan Nikolov Stranski ( bg, Иван Николов Странски; german: Iwan Nikolow Stranski; 2 January 1897 – 19 June 1979) was a Bulgarian physical chemist who is considered the father of crystal growth research. He was the founder o ...
independently proposed the same model. In 1932, Kossel took the appointment as ordinarius professor of theoretical physics at the Technische Hochschule Danzig. During his tenure there in 1934, he discovered x-ray lattice interference of spherical waves in crystals during the bombardment of single-crystal copper with a high-energy electron beam. In 1944, he was awarded the
Max-Planck medal The Max Planck medal is the highest award of the German Physical Society , the world's largest organization of physicists, for extraordinary achievements in theoretical physics. The prize has been awarded annually since 1929, with few exceptions, ...
by the
Deutsche Physikalische Gesellschaft The German Physical Society (German: , DPG) is the oldest organisation of physicists. The DPG's worldwide membership is cited as 60,547, as of 2019, making it the largest physics society in the world. It holds an annual conference () and multiple ...
. In 1945, Kossel became professor of theoretical physics and director of the Physics Institute at the
University of Tübingen The University of Tübingen, officially the Eberhard Karl University of Tübingen (german: Eberhard Karls Universität Tübingen; la, Universitas Eberhardina Carolina), is a public research university located in the city of Tübingen, Baden-Wü ...
, where he was granted emeritus status in 1953. Kossel died in
Tübingen Tübingen (, , Swabian: ''Dibenga'') is a traditional university city in central Baden-Württemberg, Germany. It is situated south of the state capital, Stuttgart, and developed on both sides of the Neckar and Ammer rivers. about one in thr ...
, and is buried, as is his father, Albrecht, in the Wald Friedhof, Heidelberg.50 Years of X-ray Diffraction: Germany
an

/ref>


Selected bibliography

*Walther Kossel ''Bemerkung zur Absorption homogener Röntgenstrahlen'', ''Verh. D. Deutsch. Phys Ges'' (2) 16 898-909 (1914). Received 27 September 1914, published in issue No. 20 of 30 October 1914. As cited in Mehra, Volume 1, Part 2, 2001, p. 795. *Walther Kossel ''Bemerkung zur Absorption homogener Röntgenstrahlen. II'', ''Verh. D. Deutsch. Phys Ges'' (2) 16 953-963 (1914). Received 23 October 1914, published in issue No. 22 of 30 November 1914. As cited in Mehra, Volume 5, Part 2, 2001, p. 919. *Walther Kossel ''Bemerkung zum Seriencharakter der Röntgenstrahlen'', ''Verh. D. Deutsch. Phys Ges'' (2) 18 339-359 (1916). Received 31 August 1916, published in issue No. 15-18 of 30 September 1916. As cited in Mehra, Volume 5, Part 2, 2001, p. 919. * Walther Kossel, “Uber Molkulbildung als Frage der Atombau”, Ann. Phys., 1916, 49:229-362.


Notes


References

*Borisenko, Victor E. and Stefano Ossicini ''What is What in the Nanoworld: A Handbook on Nanoscience and Nanotechnology''(Wiley-VCH, 2004) *Cao, Gouzhong ''Nanostructures and Nanomaterials: Synthesis, Properties, and Applications'' (Imperial College Press, 2004) *
Gerhard Herzberg Gerhard Heinrich Friedrich Otto Julius Herzberg, (; December 25, 1904 – March 3, 1999) was a German-Canadian pioneering physicist and physical chemist, who won the Nobel Prize for Chemistry in 1971, "for his contributions to the knowledge o ...
translated from German with the help of the author by J. W. T. Spinks ''Atomic Spectra and Atomic Structure'' (Dover, 1945) * Mehra, Jagdish, and
Helmut Rechenberg Helmut Rechenberg (born November 6, 1937, in Berlin; died November 10, 2016, in Munich) was a German physicist and science historian. Rechenberg studied mathematics, physics and astronomy at the University of Munich and graduated in 1964. At Mun ...
''The Historical Development of Quantum Theory. Volume 1 Part 2 The Quantum Theory of Planck, Einstein, Bohr and Sommerfeld 1900 – 1925: Its Foundation and the Rise of Its Difficulties.'' (Springer, 2001) *Mehra, Jagdish, and Helmut Rechenberg ''The Historical Development of Quantum Theory. Volume 5 Erwin Schrödinger and the Rise of Wave Mechanics. Part 2 Schrödinger in Vienna and Zurich 1887-1925.'' (Springer, 2001) * Pauling, Linus ''The Nature of the Chemical Bond and the Structure of Molecules and Crystals: An Introduction to Modern Structural Chemistry'' (Cornell, 1960) * White, Harvey Elliott ''Introduction to Atomic Spectra'' (McGraw-Hill, 1934) {{DEFAULTSORT:Kossel, Walther 1888 births 1956 deaths 20th-century German physicists Scientists from Berlin People from the Province of Brandenburg Quantum physicists Winners of the Max Planck Medal